Sequenced cyclizations involving intramolecular capture of alkyl-oxyaminyl radicals. Synthesis of heterocyclic compounds

Luz Marina Jaramillo-Gómez, Alix Elena Loaiza, Jaime Martin, Luz Amalia Ríos, Peng George Wang

Producción: Contribución a una revistaArtículorevisión exhaustiva

12 Citas (Scopus)

Resumen

A cascade radical cyclization process involving oxime ethers tethered to a brominated phenyl and an activated olefin moiety is described. The generated aryl radicals using tri-n-butyltin hydride react with the C{double bond, long}N bond to yield neutral alkyl-oxyaminyl radicals, which were then simultaneously captured by the activated double bond to provide heterocyclic systems with a pyrrolidinic nucleus.

Idioma originalInglés
Páginas (desde-hasta)3909-3912
Número de páginas4
PublicaciónTetrahedron Letters
Volumen47
N.º23
DOI
EstadoPublicada - 05 jun. 2006
Publicado de forma externa

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