4,6-Diamino-2-morpholino-5-nitrosopyrimidine: a polarized molecular structure within hydrogen-bonded sheets

Angélica García; Braulio Insuasty; Justo Cobo; Christopher Glidewell

doi:10.1107/S0108270109041122

4,6-Diamino-2-morpholino-5-nitrosopyrimidine: a polarized molecular structure within hydrogen-bonded sheets

Angélica García
, Braulio Insuasty
, Justo Cobo
, Christopher Glidewell

Universidad del Valle
University of Jaén
University of St Andrews

Producción: Contribución a una revista › Artículo › revisión exhaustiva

2 Citas (Scopus)

Resumen

In the title compound, C(8)H(12)N(6)O(2), the molecular dimensions provide evidence for significant polarization of the electronic structure. There is an intramolecular N-H...N hydrogen bond, and the molecules are linked into complex sheets by a combination of two-centre hydrogen bonds, one each of the N-H...N and N-H...O types, and a three-centre N-H...(N,O) hydrogen bond.

Idioma original	Inglés
Páginas (desde-hasta)	O598-O600
Número de páginas	3
Publicación	Acta Crystallographica Section C-structural Chemistry
Volumen	65
N.º	12
DOI	https://doi.org/10.1107/S0108270109041122
Estado	Publicada - 2009
Publicado de forma externa	Sí

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title = "4,6-Diamino-2-morpholino-5-nitrosopyrimidine: a polarized molecular structure within hydrogen-bonded sheets",

abstract = "In the title compound, C8H12N6O 2, the mol-ecular dimensions provide evidence for significant polarization of the electronic structure. There is an intra-molecular N - H⋯N hydrogen bond, and the mol-ecules are linked into complex sheets by a combination of two-centre hydrogen bonds, one each of the N - H⋯N and N - H⋯O types, and a three-centre N - H⋯(N,O) hydrogen bond.",

author = "Ang{\'e}lica Garc{\'i}a and Braulio Insuasty and Justo Cobo and Christopher Glidewell",

year = "2009",

doi = "10.1107/S0108270109041122",

language = "English",

volume = "65",

pages = "O598--O600",

journal = "Acta Crystallographica Section C-structural Chemistry",

issn = "2053-2296",

publisher = "John Wiley \& Sons Inc.",

number = "12",

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TY - JOUR

T1 - 4,6-Diamino-2-morpholino-5-nitrosopyrimidine: a polarized molecular structure within hydrogen-bonded sheets

AU - García, Angélica

AU - Insuasty, Braulio

AU - Cobo, Justo

AU - Glidewell, Christopher

PY - 2009

Y1 - 2009

N2 - In the title compound, C8H12N6O 2, the mol-ecular dimensions provide evidence for significant polarization of the electronic structure. There is an intra-molecular N - H⋯N hydrogen bond, and the mol-ecules are linked into complex sheets by a combination of two-centre hydrogen bonds, one each of the N - H⋯N and N - H⋯O types, and a three-centre N - H⋯(N,O) hydrogen bond.

AB - In the title compound, C8H12N6O 2, the mol-ecular dimensions provide evidence for significant polarization of the electronic structure. There is an intra-molecular N - H⋯N hydrogen bond, and the mol-ecules are linked into complex sheets by a combination of two-centre hydrogen bonds, one each of the N - H⋯N and N - H⋯O types, and a three-centre N - H⋯(N,O) hydrogen bond.

UR - https://www.scopus.com/pages/publications/72649098359

U2 - 10.1107/S0108270109041122

DO - 10.1107/S0108270109041122

M3 - Article

C2 - 19966439

AN - SCOPUS:72649098359

SN - 2053-2296

VL - 65

SP - O598-O600

JO - Acta Crystallographica Section C-structural Chemistry

JF - Acta Crystallographica Section C-structural Chemistry

IS - 12

ER -

4,6-Diamino-2-morpholino-5-nitrosopyrimidine: a polarized molecular structure within hydrogen-bonded sheets

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