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Virial equation of state for natural gas systems

  • J. F. Estela-Uribe
  • , J. Jaramillo
  • , M. A. Salazar
  • , J. P.M. Trusler
  • Universidad Javeriana
  • Imperial College London

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

We present a new virial equation of state for natural gas systems under 'custody transfer conditions', defined at 270≤T(K)≤330 and P≤12MPa. This model predicts compression factors of natural gases with at least the same accuracy as the well-known GERG virial equation of state. However, the model is devised in such a way that the prediction of caloric properties, particularly the speed of sound, is significantly improved with respect to the GERG virial equation. This was achieved by representing the second and third virial coefficients as quadratic functions of inverse temperature. When the new model was compared with a large database of experimental results, the overall absolute average deviation in compression factors was 0.034% while that in speeds of sound was 0.17%.

Original languageEnglish
Pages (from-to)169-182
Number of pages14
JournalFluid Phase Equilibria
Volume204
Issue number2
DOIs
StatePublished - 15 Feb 2003

Keywords

  • Compression factor
  • Density
  • Equation of state
  • Speed of sound
  • Virial coefficients

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