TY - JOUR
T1 - Symmetry properties and electronic band structure of ordered Zn 0.5Cd0.5Se alloys
AU - Salcedo-Reyes, J. C.
AU - Hernández-Calderón, I.
N1 - Funding Information:
This work was partially supported by the Conacyt-Mexico. JCSR thanks SRE-Mexico, Conacyt-Mexico and Cinvestav for scholarships at different stages of this work.
PY - 2005/3
Y1 - 2005/3
N2 - Along the [001] direction of a zincblende semiconductor we find a sequence of cation-anion planes. In the case of a random zincblende ternary alloy of the type A1-xBxC the A and B cations are randomly distributed in each cation plane. In the particular case, when x=0.5, another possible arrangement is the sequence A-C-B-C-A-C...; we can describe this crystal as an (AC)1(BC)1 superlattice, however, it is not a true superlattice, it is one of the possible ordered structures that we can obtain with A0.5B0.5C composition. This ternary alloy has the simple tetragonal structure, in contrast with the fcc crystalline structure of the random alloy with the same composition. Here, we present the results for the electronic band structure of the ordered Zn0.5Cd0.5Se alloy qualitatively determined by means of a comparative analysis of the symmetry properties of both crystals. The volume reduction of the first Brillouin zone (1BZ) of the tetragonal alloy, in relation to the cubic alloy, gives place to band folding effects. They are advantageously employed to describe the band structure of the ordered alloys in terms of the random one. Band gap reduction, removal of degeneracy at some symmetry points of the 1BZ and the doubling of the number of bands is concluded for the ordered alloy compared to the ordered one. A quite good agreement is obtained when comparing the ordered band structure obtained by symmetry arguments with an empirical tight binding calculation.
AB - Along the [001] direction of a zincblende semiconductor we find a sequence of cation-anion planes. In the case of a random zincblende ternary alloy of the type A1-xBxC the A and B cations are randomly distributed in each cation plane. In the particular case, when x=0.5, another possible arrangement is the sequence A-C-B-C-A-C...; we can describe this crystal as an (AC)1(BC)1 superlattice, however, it is not a true superlattice, it is one of the possible ordered structures that we can obtain with A0.5B0.5C composition. This ternary alloy has the simple tetragonal structure, in contrast with the fcc crystalline structure of the random alloy with the same composition. Here, we present the results for the electronic band structure of the ordered Zn0.5Cd0.5Se alloy qualitatively determined by means of a comparative analysis of the symmetry properties of both crystals. The volume reduction of the first Brillouin zone (1BZ) of the tetragonal alloy, in relation to the cubic alloy, gives place to band folding effects. They are advantageously employed to describe the band structure of the ordered alloys in terms of the random one. Band gap reduction, removal of degeneracy at some symmetry points of the 1BZ and the doubling of the number of bands is concluded for the ordered alloy compared to the ordered one. A quite good agreement is obtained when comparing the ordered band structure obtained by symmetry arguments with an empirical tight binding calculation.
KW - Band gap narrowing
KW - Electronic band structure
KW - Group theory
KW - Ordered alloys
KW - Superlattices
KW - ZnCdSe
UR - http://www.scopus.com/inward/record.url?scp=33644548010&partnerID=8YFLogxK
U2 - 10.1016/j.mejo.2005.02.122
DO - 10.1016/j.mejo.2005.02.122
M3 - Conference article
AN - SCOPUS:33644548010
SN - 0026-2692
VL - 36
SP - 342
EP - 346
JO - Microelectronics Journal
JF - Microelectronics Journal
IS - 3-6
ER -